Product ID:VOA CALIBRATION MIX # 5, 30010, 30010-5XX, 30110
MSDS Date:08/13/1995
FSC:NIIN:Submitter:N EN
Status Code:A
Kit Part:Y
MSDS Number: CLFSW

RESTEK CORPORATION

110 BENNER CIRCLE
BELLEFONTE, PA 16823-8812
US

Emergency Phone: 814-353-1300

Info Phone: 814-353-1300

Cage: OJL17

RESTEK CORP

BELLEFONTE, PA 16823-8812 US

Telephone: 814-353-1300

Cage: OJL17

METHANOL

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 260 MG/M3;200 PPM

ACGIH TLV: 262 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VINYL CHLORIDE

CAS: 75-01-4

RTECS: KU9625000

OSHA PEL 1 PPM

ACGIH TLV: 13 MG/M3;5 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CHLOROMETHANE

CAS: 74-87-3

RTECS: PA6300000

OSHA PEL 50 PPM

ACGIH TLV: 103 MG/M3;50 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

CHLOROETHANE

CAS: 75-00-3

RTECS: KH7525000

OSHA PEL 2600 MG/M3;1000 PPM

ACGIH TLV: 2640 MG/M3;1000 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BROMOMETHANE

CAS: 74-83-9

RTECS: PA4900000

OSHA PEL 5 PPM

ACGIH TLV: 19 MG/M3;5 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:CANCER HAZARD. CONTAINS VINYL CHLORIDE
WHICH IS LISTED AS A LIVER, LUNG, BRAIN & HAEMOTOLYMPHOPOIETIC
CARCINOGEN. INHALATION: EXPOSURE CAN CAUSE DROWSINESS AND
INTOXICATION, HEADACHE, VISUAL DISTURBAN CE LEADING TO BLINDNESS,
COUGHING AND SHORTNESS OF BREATH, COLLAPSE AND DEATH AT HIGH
CONCENTRATIONS. EYE CONTACT: LIQUID CAN CAUSE MODERATE BURNING,
WATERING, SWELLING, AND REDNESS. SKIN CONTACT: EXT ENSIVE, REPEATED
AND/OR PROLONGED SKIN CONTACT CAN CAUSE BURNING, ITCHING, REDNESS,
OR BLISTERS. INGESTION: CAUSES BURNING OF THE GASTROINTESTINAL
TRACT AND TOXIC EFFECTS. SWALLOWING MORE THAN 2 OUNCE S OF METHANOL
(EFFECTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:COMPONENTS LISTED AS CARCINOGENS OR
POTENTIAL CARCINOGENS: VINYL CHLORIDE: IARC GROUP 1, SUPPLEMENT 7,
PAGE 383, 1987; NTP NINTH ANNUAL REPORT KNOWN TO BE HUMAN
CARCINOGENS LIST; OSHA REGULATED 29 CFR 1910.1017.
Effects of Overexposure:HEALTH HAZARD ACUTE AND CHRONIC (CONTD): CAN
CAUSE DEATH. MILD POISONING IS CHARACTERIZED BY FATIGUE, NAUSEA,
HEADACHE, AND DELAYED VISUAL BLURRING. MODERATE INTOXICATION
RESULTS IN SEVERE DEPRESSION. TEMPORARY OR PERMANENT BLINDNESS MAY
FOLLOW IN 2-6 DAYS. IN SEVERE POISONING, SYMPTOMS PROGRESS TO
RAPID, SHALLOW RESPIRATION, CYANOSIS, COMA, HYPOTENSION, DILATED
PUPILS, AND VISUAL DISTURBANCE. DEA TH MAY RESULT FROM RESPIRATORY
FAILURE.
Medical Cond Aggravated by Exposure:DERMATITIS, DISEASES OF EYES,
LIVER, KIDNEYS, LUNGS, AND CARDIOVASCULAR SYSTEM.

First Aid:EYES: REMOVE CONTACT LENSES IF PRESENT. HOLD EYELIDS OPEN AND
IRRIGATE WITH LARGE VOLUME OF WATER FOR 15 MIN. SEEK MEDICAL
TREATMENT. SKIN: IMMEDIATELY WASH WITH SOAP AND WATER. CONTINUE
RINSING WITH LARGE VOLUME OF WATER FOR 15 MIN. REMOVE CONTAMINATED
CLOTHING. SEEK MEDICAL TREATMENT. INHALATION: IF INHALED, REMOVE TO
FRESH AIR. HAVE A TRAINED PERSON ADMINISTER OXYGEN AND CPR IF
NEEDED. CONTACT A PHYSICIAN IMMEDIATELY. INGESTION: INGESTION MAY
CAUSE BLINDNESS. CONTACT A POISON CONTROL CENTER FOR ASSISTANCE.
CONTACT A PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO A
VICTIM UNCONSCIOUS OR HAVING CONVULSIONS.

Flash Point Method:CC
Flash Point:=12.C, 53.6F
Autoignition Temp:=385.C, 725.F
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:DRY CHEMICAL, CO2, ALCOHOL FOAM, WATER MIST OR FOG.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . HEAT MAY BUILD PRESSURE
AND RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE-EXPOSED CONTAINERS
COOL WITH WATER SPRAY. MAY BURN WITH AN INVISIBLE FLAME. MIXTURES
WITH WATER AS LOW AS 21% BY VOLUME ARE STILL FLAMMABLE. (EXPLO HAZ)
Unusual Fire/Explosion Hazard:HAZARDOUS MIXTURES OF OTHER LIQUIDS,
SOLIDS, OR GASES: INCOMPLETE COMBUSTION CAN GENERATE CARBON
MONOXIDE AND OTHER TOXIC VAPORS SUCH AS FORMALDEHYDE. FIRE FIGHT
PROC (CONT): UNDER SOME CIRCUMSTANCE S CAN CORRODE CERTAIN METALS,
INCLUDING ALUMIUM AND ZINC, AND GENERATE HYDROGEN GAS.

Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. PROTECT
FROM IGNITION. ABSORB SMALL SPILLS ON PAPER, VERMICULITE, OR OTHER
ABSORBENT. COLLECT AND STORE IN CLOSED CONTAINER FOR DISPOSAL.

Handling and Storage Precautions:CONTAINS CARCINOGENS OR SUSPECTED
CARCINOGENS. AVOID ALL INHALATION AND CONTACT. KEEP IN A TIGHTLY
CLOSED CONTAINER AT ALL TIMES. PROTECT FROM TEMPERATURE EXTREMES
AND DIRECT SUNLIGHT. HANDLE WITH THE UTMOST CARE. STORE IN AN
EXPLOSION PROOF FREEZER AT -18C.
Other Precautions:VARIOUS GOVERNMENT AGENCIES (I.E., DEPARTMENT OF
TRANSPORTATION, OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION,
ENVIRONMENTAL PROTECTION AGENCY, AND OTHERS) MAY HAVE SPECIFIC
REGULATIONS CONCERNING TH E TRANSPORTATION, HANDLING, STORAGE OR
USE OF THIS PRODUCT WHICH MAY NOT BE CONTAINED HEREIN. THE CO
NSUMER (OTHER INFO)

Respiratory Protection:A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN . FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S
RECOMMENDATIONS TO DETERMINE APPROPRIATE RESPIRATOR.
Ventilation:USE IN AN AREA PROVIDED WITH GENERAL AND LOCAL EXHAUST
VENTILATION MEETING OSHA REQUIREMENTS.
Protective Gloves:SOLVENT RESISTANT NEOPRENE, NITRILE, OR RUBBER.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . PROTECTIVE CLOTHING MEETING LABORATORY SAFETY
REQUIREMENTS.
Supplemental Safety and Health
ADDITIONAL INFORMATION ON INGREDIENTS: % COMPOSITION: COMPONENTS ARE
CALCULATED ON A WEIGHT/VOLUME BASIS. PHYSICAL/CHEMICAL PROPERTIES
(CONT'D): LIQUID DENSITY: .791 @ 20 C. OTHER PRECAUTIONS (CON
T'D): OR USER OF THIS PRODUCT SHOULD BE FAMILIAR WITH THESE
REGULATIONS.

Boiling Pt:=65.C, 149.F
Vapor Pres:97MM HG @ 20C.
Solubility in Water:MISCIBLE.
Appearance and Odor:COLORLESS/ ALCOHOL ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND REACTIVE METALS WHICH WILL DISPLACE
HYDROGEN.
Stability Condition to Avoid:HEAT, SPARKS, AND CONTACT WITH IGNITION
SOURCE.

Waste Disposal Methods:INCINERATE AT AN APPROVED FACILITY IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Toxicological Information:CONSULT RTECS FOR COMPLETE INFORMATION ON THE
EFFECTS OF THIS COMPOUND.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:WARNING: CONTAINS BROMOMETHANE, A SUBSTANCE WHICH HARMS
HUMAN HEALTH AND ENVIRONMENT BY DESTROYING OZONE IN THE UPPER
ATMOSPHERE.

State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: CHLOROETHANE,
75-00-3 RTECS # KH7525000, B ROMOMEHTANE, 74-83-9.